Uranotungstite

Chemical formula: Ba(U<sup>6+</sup>O<sub>2</sub>)<sub>2</sub>W<sup>6+</sup><sub>2</sub>O<sub>8</sub>(OH)<sub>2</sub>·H<sub>2</sub>O

Uranotungstite is a very rare, radioactive secondary mineral, a hydrated uranyl and barium tungstate, found in the oxidation zones of tungsten deposits.

## Characteristics Uranotungstite is an extremely rare secondary mineral, formed by the oxidation of tungsten and uranium minerals. It forms very small, thin, bladed or acicular crystals, which typically form rosette-like or stellar aggregates, as well as spherulitic masses and crusts. Individual crystals rarely exceed 0.2 mm in length. Due to its chemical composition, this mineral is strongly radioactive. ## Physical Properties Uranotungstite crystals exhibit a vitreous to pearly luster, especially on cleavage surfaces. They are transparent to translucent. Hardness and density have not been precisely determined due to the small size and rarity of the crystals. ## Colors and Varieties This mineral is characterized by an intense, canary-yellow color. No varieties are known. ## History and Name Uranotungstite was first described in 1985 by a team of mineralogists (Walenta, Wimmenauer, Dunn) based on samples from the Clara mine in the Rankach Valley, Black Forest (Germany). The name directly refers to the mineral's chemical composition, indicating the presence of uranium (Urano-) and tungsten (-tungstite).

Properties

Mohs hardness
2
Luster
Vitreous to Pearly
Streak
Light yellow
Density
6.35
Cleavage
Perfect on {010}
Fracture
Uneven
Transparency
Transparent to translucent
Crystal system
Orthorhombic

Diagnostic features

## Identification Key diagnostic features of uranotungstite include its characteristic canary-yellow color, specific crystal forms (thin blades forming rosette-like or stellar aggregates), and strong radioactivity. This mineral also exhibits intense, greenish-yellow fluorescence under ultraviolet light (both shortwave and longwave). ## Distinguishing from Similar Minerals Uranotungstite can be confused with other yellow secondary uranium minerals, such as uranophane, boltwoodite, or cuprosklodowskite. Distinguishing it requires advanced analytical methods, such as X-ray diffraction (XRD) or chemical analysis (EDS/WDS), due to visual similarities and co-occurrence. The characteristic stellar aggregates can be a helpful visual clue. ## Crystal Forms Uranotungstite crystallizes as very small, thin, bladed crystals, elongated along the [100] axis and flattened parallel to {010}. These crystals often combine to form stellar or rosette-like aggregates, as well as radial and spherulitic masses and thin crusts on the host rock.

Geological environment

## Genesis Uranotungstite is a secondary mineral that forms in the oxidation zones of hydrothermal deposits containing tungsten minerals (mainly wolframite and scheelite) and uranium (uraninite). It forms as a result of surface waters acting on these primary minerals under conditions of low temperatures and pressures. ## Mineral Associations This mineral co-occurs with other secondary uranium and tungsten minerals. In its type locality (Clara mine), it was found in association with uraninite, wolframite, scheelite, hematite, quartz, barite, fluorite, and other rare secondary minerals such as stolzite, tungstite, cuprosklodowskite, uranophane, and kasolite. ## Localities Uranotungstite is an extremely rare mineral. Besides its type locality – the Clara mine in the Black Forest, Germany – its occurrence has been confirmed in only a few other places worldwide, including the La Muela mine in Ponferrada (Spain) and the Carrizal area in Chile.

Rarity

Extremely rare

For collectors

## Quality Criteria Due to its extreme rarity, every confirmed specimen of uranotungstite is valuable for specialized collections. Micromounts showing well-formed, stellar or rosette-like crystal aggregates of intense, canary-yellow color are most highly prized. The aesthetic composition with associated minerals on a small fragment of host rock is also important. ## Popular Localities The vast majority of the best and most well-known uranotungstite specimens come from its type locality – the Clara mine in the Rankach Valley, Black Forest (Germany). This is a classic locality for many rare secondary minerals.

Care and storage

## Cleaning Due to its extreme rarity, small size, and fragility of crystals, mechanical cleaning is inadvisable and practically impossible. Specimens should be protected from dust. ## What to Avoid Uranotungstite is a stable mineral, but contact with chemicals and ultrasonic cleaners should be avoided. As a radioactive mineral, it requires safe handling and storage away from other minerals that could be damaged by radiation. Inhaling dust and direct skin contact should be avoided. ## Storage Uranotungstite specimens should be stored in specialized, lead-lined containers or in a way that minimizes radiation exposure. They should be kept in a dry place, away from sunlight, and in a well-ventilated room. Containers should always be clearly labeled as containing radioactive material.

Sources

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