Tlapallite

Chemical formula: (Ca,Pb<sup>2+</sup>)<sub>3</sub>CaCu<sup>2+</sup><sub>6</sub>[Te<sup>4+</sup><sub>3</sub>Te<sup>6+</sup>O<sub>12</sub>]<sub>2</sub>(Te<sup>4+</sup>O<sub>3</sub>)<sub>2</sub>(S<sup>6+</sup>O<sub>4</sub>)<sub>2</sub>·3H<sub>2</sub>O

Tlapallite is a very rare copper, calcium, and lead tellurate, forming microscopic, green coatings and aggregates.

## Characteristics Tlapallite is a secondary mineral found in the oxidation zones of tellurium-rich ore deposits. It forms very fine, spherical aggregates, rosettes, or earthy coatings and crusts. Its crystals, rarely exceeding 0.1 mm, are in the form of hexagonal plates. Due to the small size of the crystals, visual features are difficult to observe without a microscope. ## Physical Properties This mineral is very soft, with a Mohs hardness of approximately 3. The luster is described as earthy or dull. It is opaque. Due to its microscopic nature, density has not been precisely measured. ## Colors and Varieties Tlapallite is characterized by a vivid green color, often described as emerald green or grass green. No varieties have been distinguished. ## History and Name The mineral was discovered in the La Moctezuma mine (Bambolla) in Mexico and described in 1978 by Sidney A. Williams. The name comes from the Nahuatl word "tlapalli," meaning "paint" or "dye," which refers to its intensely green color and earthy appearance resembling a pigment. ## Uses Due to its extreme rarity and microscopic occurrence, tlapallite has no industrial applications. It is solely an object of interest for collectors specializing in rare minerals and scientists.

Properties

Mohs hardness
3
Luster
Earthy
Streak
Light green
Cleavage
Perfect on {0001}
Fracture
Uneven
Transparency
Opaque
Crystal system
Hexagonal

Diagnostic features

## Identification Identification of tlapallite is based on its characteristic emerald-green color, earthy or spherical aggregates, and occurrence in association with other rare tellurates and tellurides. Identification is practically only possible under laboratory conditions using advanced analytical methods (e.g., EDS/WDS, XRD) due to the microscopic size of the crystals. ## Distinguishing from Similar Minerals Tlapallite can be confused with other secondary green copper minerals, such as malachite, brochantite, or other rare tellurates (e.g., quetzalcoatlite, xocomecatlite). Visual distinction is impossible. Tlapallite is distinguished by its unique chemical composition, containing tellurium in two oxidation states (Te⁴⁺ and Te⁶⁺), sulfate, copper, lead, and calcium simultaneously. ## Crystal Forms The mineral forms microscopic, hexagonal plates that combine into spherical or rosette-like aggregates. It often occurs as earthy, powdery coatings and thin crusts on the surface of the host rock.

Geological environment

## Genesis Tlapallite is a secondary mineral, formed in the oxidation (weathering) zone of hydrothermal deposits rich in tellurium, copper, and lead. It forms under low-temperature conditions as a result of the alteration of primary tellurides. ## Mineral Associations This mineral co-occurs with other, often equally rare, minerals of the oxidation zone. The most common associations include: native tellurium, quartz, baryte, as well as tellurates and tellurides such as quetzalcoatlite, xocomecatlite, eztlite, carlfriesite, emmonsite, and teineite. ## Localities The most important and historical locality for tlapallite is its type locality – the La Moctezuma mine (also known as Bambolla) in Sonora, Mexico. It has also been identified in the Emerald mine in the Tombstone district, Arizona (USA), and in the Kawazu mine in Shizuoka Prefecture, Japan.

Rarity

Very rare

For collectors

## Quality Criteria For tlapallite, as a "micromount" type mineral, the most important criterion is the richness and aesthetics of the microscopic aggregates on the rock matrix. Specimens with clearly formed, spherical or rosette-like clusters of intense, emerald-green color are most highly valued. Association with other rare minerals is also important, as it increases the scientific and collectible value of the specimen. ## Popular Localities Specimens from the type locality – the La Moctezuma mine in Mexico – are by far the most valued and sought after by collectors. Material from the Emerald mine in Arizona is also known, but Mexican specimens are considered classic for this species.

Care and storage

## Cleaning Tlapallite specimens should not be cleaned mechanically or chemically. Any attempts at cleaning can irreversibly damage the delicate, microscopic aggregates. If dust removal is necessary, it can be done very carefully with a soft brush or a photographic air blower, avoiding direct contact with the mineral. ## What to Avoid Avoid contact with water, acids, solvents, and all chemical agents. The mineral is very soft and susceptible to abrasion. Protect it from vibrations, shocks, and temperature changes. ## Storage Tlapallite specimens should be stored exclusively in sealed, closable "micromount" boxes to protect them from dust, mechanical damage, and moisture. They should not be exposed to direct sunlight.

External references

Sources

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