Stibiogoldfieldite

Chemical formula: Cu<sup>1+</sup><sub>6</sub>Cu<sup>1+</sup><sub>6</sub>(Sb<sup>3+</sup><sub>2</sub>Te<sup>4+</sup><sub>2</sub>)S<sup>2-</sup><sub>13</sub>

Stibiogoldfieldite is a very rare sulfosalt mineral, an antimony analog of goldfieldite, found as small, metallic grains.

## Characteristics Stibiogoldfieldite is a very rare sulfosalt mineral belonging to the tetrahedrite group. It is an antimony (Sb) analog of goldfieldite, in which antimony dominates over tellurium. It usually occurs as very fine, irregular grains, often intergrown with other ore minerals. Due to the microscopic size of its crystals, its macroscopic features are difficult to observe. It has a steel-gray to black color and a metallic luster. ## Physical Properties This mineral is characterized by a metallic luster and is opaque. Its Mohs hardness ranges from 3 to 3.5, classifying it as a relatively soft mineral. The density calculated based on its chemical formula and unit cell parameters is approximately 5.07 g/cm³. ## History and Name The name "stibiogoldfieldite" refers to its chemical composition – the dominance of antimony (Latin: *stibium*) – and its relation to the structurally similar mineral, goldfieldite. It was formally described as a new mineral by E.M. Spiridonov and co-workers in 1981. Type specimens come from the Kajaran deposit in Armenia.

Properties

Mohs hardness
3-3.5
Luster
Metallic
Streak
Black
Density
5.07
Cleavage
None
Fracture
Uneven
Transparency
Opaque
Crystal system
Isometric

Diagnostic features

## Identification Identification of stibiogoldfieldite is impossible without advanced laboratory techniques. It requires chemical analysis (e.g., using an electron microprobe - EDS/WDS) to confirm the dominance of antimony over tellurium, and X-ray diffraction (XRD) analysis to confirm its crystal structure. In polished ore sections under a reflected light microscope, it appears gray. ## Distinguishing from Similar Minerals Stibiogoldfieldite is visually indistinguishable from other minerals of the tetrahedrite group, such as tetrahedrite, tennantite, goldfieldite, or arsenogoldfieldite. Differentiation relies solely on precise chemical analysis. ## Crystal Forms This mineral primarily forms anhedral (irregular) grains, typically not exceeding a few tens of micrometers in size. Poorly formed, small crystals with a tetrahedral habit, typical for minerals of its group, are rarely observed.

Geological environment

## Genesis Stibiogoldfieldite forms under hydrothermal conditions, in ore veins of medium and low formation temperatures. It is a product of crystallization from solutions rich in copper, sulfur, antimony, and tellurium. ## Mineral Associations It most often co-occurs with other minerals of the tetrahedrite group (goldfieldite, tetrahedrite), as well as with chalcopyrite, bornite, enargite, luzonite, pyrite, sphalerite, galena, and gold and silver tellurides (e.g., sylvanite, hessite). ## Localities The most important and confirmed occurrences of this very rare mineral are: - Kajaran (Kajaran) copper-molybdenum deposit in Syunik Province, Armenia (type locality). - Ozernovskoe deposit in Kamchatka, Russia. - Mohawk Mine in Goldfield, Esmeralda County, Nevada, USA.

Rarity

Very rare

For collectors

## Quality Criteria Stibiogoldfieldite specimens are not evaluated for aesthetic appeal, as the mineral occurs as microscopic grains. The collector and scientific value of a specimen lies in the confirmation of the mineral's presence through chemical analysis. The most valuable samples are those from the type locality (Kajaran) or rich associations with other rare sulfosalts and tellurides, where stibiogoldfieldite forms relatively "large" (on a micro-scale) and chemically pure grains.

Care and storage

## Cleaning Stibiogoldfieldite specimens, due to their microscopic nature and occurrence as inclusions in other minerals, are practically impossible to clean under amateur conditions. Any attempts at mechanical or chemical cleaning may destroy the delicate grains. ## What to Avoid Avoid contact with chemicals, especially acids, which can react with sulfides. Also, avoid ultrasound and high temperatures, which could damage the specimen or the entire rock matrix. ## Storage Specimens containing stibiogoldfieldite should be stored under stable conditions, in a dry place, away from direct sunlight and contaminants. It is best to store them in labeled collector boxes to prevent mechanical damage and identification errors.

Sources

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