Selenodantopaite

Chemical formula: Ag¹⁺₅Bi³⁺₁₃Se²⁻₂₂

Selenodantopaite is a rare silver-bismuth selenide, forming microscopic, metallic inclusions in other minerals.

## Characteristics Selenodantopaite is a very rare mineral from the sulfosalt group, specifically a silver-bismuth selenide. It occurs as microscopic, anhedral (irregularly shaped) grains, usually as inclusions in other minerals, most commonly in clausthalite. Its maximum observed dimensions do not exceed 150 micrometers. It is typically indistinguishable to the naked eye and requires laboratory analysis. ## Physical Properties Due to the microscopic size of the crystals, most physical properties have not been precisely determined. The mineral exhibits a strong, metallic luster. It is opaque. Hardness and density have not been measured, but the density calculated based on the chemical formula and unit cell parameters is 8.11 g/cm³. ## Colors and Varieties Observed in reflected light under a microscope, selenodantopaite has a creamy white color with a slight yellowish tint. It does not exhibit pleochroism or internal reflections. No varieties are known. ## History and Name The mineral was first described by D.I. Kridl and co-workers in 2021. Its name refers to its structural and chemical similarity to dantopaite (Ag₅Bi₁₃S₂₂), emphasizing the dominance of selenium (Se) over sulfur (S). It was approved by the International Mineralogical Association (IMA) under number 2020-085. The type locality (locus typicus) is the historic Předbořice uranium mine in the Czech Republic. ## Uses Selenodantopaite has no practical or commercial applications. Its significance is purely scientific and as a collector's item, being a very rare and newly described mineral species.

Properties

Mohs hardness
3.5-0
Color
dark grey
Luster
Metallic
Density
7.403
Cleavage
Undetectable
Fracture
Irregular/Uneven
Transparency
Opaque
Crystal system
Monoclinic

Diagnostic features

## Identification Identification of selenodantopaite is impossible without advanced laboratory equipment. It requires analysis by reflected light microscopy and chemical analysis using an electron microprobe (EDS/WDS) to confirm its composition (dominance of Ag, Bi, and Se). It is a mineral identifiable only at the microscopic level. ## Distinguishing from Similar Minerals Under the microscope, selenodantopaite is very similar to other bismuth selenides and sulfosalts, such as dantopaite, clausthalite, bohdanowiczite, or umangite. Distinguishing it from dantopaite requires chemical analysis showing the dominance of selenium over sulfur. It differs from clausthalite by a slightly brighter hue and the lack of characteristic, perfect cleavage. ## Crystal Forms This mineral forms exclusively anhedral (irregular), rounded grains and aggregates of microscopic size, usually not exceeding 150 µm. It has not been observed in the form of well-developed crystals.

Geological environment

## Genesis Selenodantopaite forms under hydrothermal conditions, in calcite-hematite veins with selenide mineralization. At the type locality (Předbořice, Czech Republic), it is associated with low-temperature processes that led to the concentration of selenium, bismuth, and silver. ## Mineral Associations This mineral occurs in close association with clausthalite (often as inclusions within it), hematite, calcite, petroviceite, umangite, eskebornite, chameanite, uraninite, and also with its sulfur analog - dantopaite. ## Localities The only confirmed and described occurrence of selenodantopaite in the world is its type locality: the former Předbořice uranium mine, located near the town of Krásná Hora nad Vltavou in the Central Bohemian Region, Czech Republic.

Rarity

Extremely rare

For collectors

## Quality Criteria The quality of a selenodantopaite specimen is assessed solely through its scientific and locality value. Since the mineral is invisible to the naked eye, its value is determined by the richness of the mineral association on the specimen and the confirmation of selenodantopaite's presence through laboratory analysis. The specimen itself does not possess aesthetic qualities related to this specific mineral. ## Popular Localities The only source of specimens is the historic Předbořice mine in the Czech Republic. Material from this locality is extremely rare and available almost exclusively in specialized systematic collections and scientific institutions.

Care and storage

## Cleaning Specimens containing microscopic grains of selenodantopaite should be cleaned with the utmost care. The safest method is to use compressed air to remove dust. Any contact with water or chemicals is inadvisable due to the potential reactivity of associated minerals. ## What to Avoid Avoid all chemical agents, especially acids, which can damage both selenodantopaite and the surrounding minerals. Also, avoid ultrasonics and mechanical cleaning (e.g., with brushes), which could damage the delicate surface of the specimen and the microscopic inclusions. ## Storage Specimens containing selenodantopaite should be stored under stable conditions, in a dry place, away from direct sunlight and contaminants. It is best to keep them in sealed collector's boxes (so-called "membrane boxes"), which protect against dust and mechanical damage.

External references

Sources

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