Plumboagardite

Chemical formula: (Pb²⁺,REE,Ca)Cu²⁺₆(As⁵⁺O₄)₃(OH)₆·3H₂O

Plumboagardite is a rare lead-copper arsenate, forming characteristic acicular crystals of an intense blue-green color.

## Characteristics Plumboagardite is a mineral from the agardite group, belonging to the arsenate class. It is distinguished by the presence of lead as the dominant rare earth element. It forms very fine, slender crystals with an acicular or hair-like appearance, most often occurring as radial aggregates, spherical clusters, or felt-like crusts. Due to the small size of the crystals, its features are often observed at a microscopic scale. ## Physical properties Plumboagardite crystals exhibit a silky or vitreous luster. They are translucent, and in the case of very thin needles, they can appear almost transparent. The Mohs hardness is approximately 3, and the density ranges between 3.68 and 3.73 g/cm³. ## Colors and varieties This mineral is characterized by a vibrant palette of colors, from blue-green, through green, to yellowish-green. There are no named commercial or color varieties. ## History and name The name plumboagardite refers to its chemical composition – the dominance of lead (Latin: *plumbum*) and its structural similarity to agardite. It was described as a new mineral in 1980 by Dietrich, Orliac, and Permingeat based on material from the Clara mine in the Black Forest (Germany).

Properties

Mohs hardness
3
Color
Green, pale greenish
Luster
Vitreous to silky
Streak
Greenish
Density
0
Cleavage
None
Fracture
Uneven
Transparency
Translucent
Crystal system
Hexagonal

Diagnostic features

## Identification The key diagnostic feature of plumboagardite is its fine, acicular or hair-like crystals gathered in radial aggregates with a characteristic blue-green or yellowish-green color. It occurs in the oxidation zones of copper and lead ores. ## Distinguishing from similar minerals Plumboagardite is visually almost impossible to distinguish from other minerals of the mixite group (e.g., agardite-(Y), agardite-(Ce), mixite) without advanced chemical analysis (EDS/WDS) to determine the dominant rare earth element or lead. It can be confused with other secondary copper minerals, such as malachite (reacts with acid), brochantite, or olivenite, but the crystal form of plumboagardite is usually more delicate and acicular. ## Crystal forms Crystals are hexagonal, very elongated along the c-axis, forming acicular and hair-like shapes. They usually occur as radial or stellate aggregates, as well as tangled masses resembling felt or glass wool.

Geological environment

## Genesis Plumboagardite is a secondary mineral, forming in the oxidation (weathering) zones of polymetallic ore deposits rich in arsenic, copper, and lead. It forms as a result of surface waters acting on primary ore minerals. ## Mineral associations It often co-occurs with other secondary arsenate and sulfate minerals. Typical associated minerals include malachite, cerussite, mimetite, olivenite, bayldonite, duftite, anglesite, goethite, and quartz. ## Localities Important localities worldwide, from which well-formed specimens originate, include the Clara mine in the Black Forest (Germany), Laurion (Greece), Tsumeb (Namibia), Bou Skour (Morocco), and some mines in Arizona and Utah (USA).

Rarity

Rare

For collectors

## Quality criteria The most valued specimens by collectors are those with well-defined, radial aggregates of intense, vibrant color. The contrast with the rock matrix on which the crystals occur significantly enhances visual appeal. The size of the aggregates and the absence of damage to the delicate needles are also important. Specimens with well-documented localities are more highly valued. ## Popular localities Specimens from Greek Laurion are classics and highly regarded. Very aesthetic, yellowish-green aggregates come from the Bou Skour mine in Morocco. The Clara mine in Germany, being the type locality, has also provided many high-quality specimens.

Care and storage

## Cleaning Specimens should be cleaned only very carefully, using a soft brush to remove dust. Due to the fragility and delicacy of the acicular crystals, wet or mechanical cleaning is not recommended. If absolutely necessary, distilled water and compressed air can be used for drying. ## What to avoid Avoid contact with all chemicals, especially acids, which can damage the mineral. Fragile crystals are sensitive to ultrasound, vibrations, and impacts. Protect it from high temperatures and sudden temperature changes. ## Storage It is recommended to store specimens in closed, padded boxes or display cases to protect them from dust, mechanical damage, and direct contact. Avoid placing heavier minerals nearby, which could crush the delicate needles.

External references

Sources

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