Plagionite

Chemical formula: Pb<sup>2+</sup><sub>5</sub>Sb<sup>3+</sup><sub>8</sub>S<sup>2-</sup><sub>17</sub>

Plagionite is a rare lead-antimony sulfosalt, forming characteristic, thick, tabular crystals with a metallic luster and dark gray color.

## Characteristics Plagionite is a complex lead-antimony sulfosalt belonging to the plagionite group. It forms thick, tabular, often curved or distorted crystals that may exhibit striations. It typically occurs as granular aggregates or massive formations. Its color ranges from lead-gray to steel-gray, often with a dull or slightly iridescent tarnish on the surface. ## Physical Properties This mineral is relatively soft, with a Mohs hardness of 2.5. It is opaque and possesses a strong, metallic luster. It is a brittle mineral with an uneven fracture. Its density is significant, approximately 5.5-5.7 g/cm³, which is noticeable even in small specimens. ## Colors and Varieties Plagionite occurs in uniform colors. Its color ranges from lead-gray to steel-gray, and a black or dull tarnish may appear on weathered surfaces. No distinct color varieties or commercial varieties are recognized. ## History and Name The name plagionite comes from the Greek word "plagios" (πλάγιος), meaning "oblique," referring to the oblique, monoclinic nature of its crystals. The mineral was first described in 1833 by August Breithaupt based on specimens found in the Graf Jost-Christian mine in Wolfsberg, Harz Mountains, Germany. ## Applications Due to its rarity and small accumulations, plagionite has no industrial significance as an ore of lead or antimony. However, it is a valued and sought-after mineral by collectors specializing in sulfosalts.

Properties

Mohs hardness
2.5
Luster
Metallic
Streak
Black, reddish
Density
5.5-5.7
Cleavage
Poor/Indistinct on {112}
Fracture
Uneven
Transparency
Opaque
Crystal system
Monoclinic

Diagnostic features

## Identification Plagionite can be identified by its dark gray color, metallic luster, and characteristic thick, tabular crystals, which are often curved. Its relatively low hardness (2.5) and high density are also important diagnostic features. The streak is black with a reddish tint. ## Distinguishing from Similar Minerals Plagionite is sometimes confused with other lead-antimony sulfosalts, such as semseyite, zinkenite, or boulangerite. It is distinguished from semseyite by its thicker, more tabular crystal habit (semseyite forms thinner tablets, often in rosette aggregates). From zinkenite and boulangerite, which often form acicular or fibrous aggregates, it is distinguished by its crystal form. Reliable differentiation often requires advanced analytical methods, such as XRD. ## Crystal Forms Plagionite crystals are monoclinic, thickly tabular, often with a rhombic outline. Crystal surfaces can be striated. Crystals are usually small, rarely exceeding one centimeter. It also occurs in granular and massive aggregates.

Geological environment

## Genesis Plagionite is a hydrothermal mineral. It forms in ore veins that develop at low to medium temperatures, rich in antimony and lead. ## Mineral Associations It most commonly co-occurs with other lead-antimony sulfosalts, such as zinkenite, semseyite, boulangerite, as well as with galena, sphalerite, pyrite, chalcopyrite, quartz, and stibnite. ## Localities The most important historical and classic locality, from which well-formed crystals originate, is Wolfsberg in the Harz Mountains, Germany. Other known localities include Baia Sprie and Herja in Romania, the Příbram mine in the Czech Republic, and some localities in Bolivia (e.g., San José mine in Oruro) and Nevada (USA).

Rarity

Rare

For collectors

## Quality Criteria The most valued specimens by collectors are those with well-formed, sharp, undamaged crystals with a strong metallic luster. Crystals with a distinct tabular habit, set on a contrasting rock matrix, are particularly sought after. Crystal size is of great importance – specimens with crystals exceeding 1 cm are considered exceptional. Aesthetic crystal groups are much more highly prized than single, isolated crystals or massive aggregates. ## Popular Localities Classic, most prized plagionite specimens come from Wolfsberg, Germany. They serve as a historical standard for this species. High-quality specimens, often in the form of rich aggregates, also come from Romanian mines in the Maramureș region (e.g., Herja).

Care and storage

## Cleaning Plagionite specimens should be cleaned very carefully, using a soft brush to remove dust. Distilled water can be used, but prolonged soaking should be avoided, and the specimen should be thoroughly dried immediately. Ultrasonic cleaners are not recommended. ## What to Avoid Avoid contact with acids and other chemicals that can damage the mineral's surface. Plagionite is brittle, so protect it from impacts and falls. Prolonged exposure to moisture can lead to the formation of tarnish on its surface. ## Storage Plagionite specimens are best stored in stable conditions, in closed boxes or display cases, to protect them from dust, moisture, and mechanical damage. It is advisable to separate it from harder minerals that could scratch it.

Sources

Read more