Obradovicite-NaNa

Chemical formula: [Na<sub>2</sub>(H<sub>2</sub>O)<sub>16</sub>Na(H<sub>2</sub>O)<sub>6</sub>][Mo<sup>6+</sup><sub>8</sub>As<sup>5+</sup><sub>2</sub>Fe<sup>3+</sup><sub>3</sub>O<sub>33</sub>(OH)<sub>4</sub>]

Obradovicite-NaNa is a very rare sodium iron molybdate arsenate, forming microscopic, tabular crystals of an intensely green color.

## Characteristics Obradovicite-NaNa is a complex, hydrated sodium iron molybdate arsenate. It occurs as extremely small, tabular or platy crystals, rarely exceeding 0.2 mm in length. It forms rosette-like or radial aggregates, as well as thin coatings and crusts. Its most characteristic feature is an intense, emerald-green to dark-green color. ## Physical Properties Crystals exhibit a vitreous luster. Due to the microscopic size of the crystals, hardness and density have not been precisely measured. The mineral is transparent to translucent. ## History and Name The mineral was named in honor of Milivoj Obradović (1919-1996), a Serbian mineral collector who gathered the first samples. The prefix "-NaNa" refers to the dominance of sodium (Na) in two specific positions in its crystal structure. It was approved by the International Mineralogical Association (IMA) in 2008.

Properties

Mohs hardness
2
Luster
Vitreous
Streak
Light green
Density
3.45
Cleavage
Perfect on {001}
Fracture
Uneven
Transparency
Transparent to translucent
Crystal system
Triclinic

Diagnostic features

## Identification In practice, the identification of this mineral relies on its unique appearance and geological context. Characteristic features include its intensely green color, vitreous luster, and occurrence as small, tabular crystals forming rosette-like aggregates on the host rock. Final confirmation requires advanced analytical methods, such as Raman spectroscopy or X-ray diffraction (XRD). ## Distinguishing from Similar Minerals It can be confused with other secondary, green arsenic minerals, such as agardite, annabergite, or olivenite. However, it is distinguished by its specific crystal habit (thin tabular crystals in rosettes) and its co-occurrence with molybdenite and other molybdates in the oxidation zone. Most similar minerals form acicular or prismatic crystals. ## Crystal Forms Crystals are very small, thin, and tabular, with a hexagonal or platy outline. They typically form radial or rosette-like aggregates, as well as thin coatings on the rock surface.

Geological environment

## Genesis Obradovicite-NaNa is a secondary mineral, formed in the oxidation zones of molybdenum-copper deposits. It forms as a result of the weathering of primary sulfides, mainly molybdenite and pyrite, in the presence of arsenic minerals. ## Mineral Associations It most commonly co-occurs with quartz, molybdenite, pyrite, chalcopyrite, tenorite, hematite, jarosite, as well as other rare molybdates such as wulfenite and lindgrenite. ## Localities The only confirmed locality for this mineral in the world (type locality) is the abandoned Chuquicamata copper and molybdenum mine, located in the Atacama Desert in the Antofagasta region of Chile.

Rarity

Extremely rare

For collectors

## Quality Criteria The quality of Obradovicite-NaNa specimens is primarily assessed based on the richness and aesthetics of the crystal aggregates. The most prized samples are those with clearly formed, undamaged rosettes of an intensely green color, contrasting well with the light host rock (most often quartz). Crystal size, although always microscopic, is also important – larger and better-formed tabular crystals increase the value of the specimen.

Care and storage

## Cleaning Due to the extreme rarity and delicate nature of specimens, mechanical cleaning is absolutely inadvisable. Contact with water and any chemicals should be avoided. The safest method is to remove dust using compressed air from a safe distance. ## What to Avoid Vibrations, shocks, ultrasound, and any attempts at chemical or mechanical cleaning should be avoided. Specimens are sensitive to changes in humidity and temperature. They should not be exposed to direct sunlight. ## Storage Obradovicite-NaNa specimens should be stored exclusively in specialized, sealed "micromount" boxes, protecting them from dust, humidity, and mechanical damage. Store under stable room conditions.

Sources

Read more