Numanoite

Chemical formula: Ca₄Cu²⁺B₄O₆(OH)₆(CO₃)₂

Numanoite is a very rare, blue copper and calcium borate, forming microscopic, prismatic crystals in skarns.

## Characteristics Numanoite is a hydrated calcium copper carbonate borate, occurring as very small, prismatic crystals up to 0.3 mm long. It forms radial or randomly oriented clusters and aggregates. It is a transparent mineral with a vitreous luster and a characteristic, light blue color, which distinguishes it from most co-occurring minerals. ## Physical Properties Numanoite crystals exhibit a hardness of approximately 3 on the Mohs scale. The mineral has a vitreous luster and a light blue streak. It is brittle, and its density, calculated based on the chemical formula and unit cell parameters, is 2.93 g/cm³. ## Colors and Varieties Numanoite occurs in a uniform, light blue color. No color or commercial varieties have been distinguished. ## History and Name The mineral was discovered in the Fuka mine in Okayama Prefecture, Japan. Its name honors Kyoko Numano (b. 1937), a Japanese amateur mineralogist who first found this mineral. It was approved by the International Mineralogical Association (IMA) in 2007 under the number IMA2007-048. The holotype (reference specimen) is preserved in the collections of the National Museum of Nature and Science in Tokyo. ## Applications Due to its extreme rarity and microscopic crystal sizes, numanoite has no industrial applications. It is solely of scientific importance and is an object of interest for specialized collectors of rare minerals.

Properties

Mohs hardness
4.5
Color
bluish green
Luster
Vitreous
Streak
Light blue
Density
2.96
Cleavage
{100} {110}
Fracture
Uneven
Transparency
Translucent
Crystal system
Monoclinic

Diagnostic features

## Identification Numanoite can be identified by its characteristic light blue color, vitreous luster, and form of small, prismatic crystals forming radial aggregates. It occurs in a specific geological environment – calc-silicate skarns. Final identification requires advanced analytical methods, such as X-ray diffraction (XRD) or chemical analysis (EDS/WDS). ## Distinguishing from Similar Minerals Numanoite can be confused with other blue secondary copper minerals, such as azurite, but it typically forms much smaller crystals. At its locality of occurrence (Fuka mine), it co-occurs with takimotoite, which has a similar composition but crystallizes in the monoclinic system and has a darker, blue-green color. Distinguishing it from other rare copper borates is impossible without specialized equipment. ## Crystal Forms Numanoite crystals are elongated, prismatic, with a cross-section close to square. They usually occur in the form of radial or tangled aggregates, as well as single, overgrown crystals on the surface of the host rock.

Geological environment

## Genesis Numanoite is a secondary mineral, formed in the contact zone (skarn) between a granodiorite intrusion and carbonate rocks (limestones). Its formation is associated with hydrothermal and metasomatic processes, where boron- and copper-rich solutions reacted with calcareous rocks. ## Mineral Associations This mineral co-occurs with other borates and skarn minerals. At the type locality (Fuka mine), it was found in association with minerals such as: takimotoite, olshanskyite, nifontovite, borcarite, siberite, calcite, gehlenite, wollastonite, and garnets from the grossular-andradite group. ## Localities The only confirmed and described occurrence of numanoite in the world is its type locality – the Fuka mine, near Takahashi City, Okayama Prefecture, Japan.

Rarity

Extremely rare

For collectors

## Quality Criteria The quality of numanoite specimens is primarily assessed based on the richness and aesthetics of microcrystal aggregates on the rock matrix. The most prized specimens are those with clearly formed, radial clusters of intense, light blue color, contrasting well with the substrate. Due to their microscopic nature, the size of individual crystals is not a key criterion; rather, the overall appearance of the aggregate matters. ## Popular Localities The only source of numanoite specimens is the Fuka mine in Japan. Material from this locality is extremely rare and sought after by collectors specializing in rare minerals and "micromount" specimens.

Care and storage

## Cleaning Numanoite specimens are extremely delicate and usually occur as microscopic crystals on a rock matrix. Mechanical or chemical cleaning is not recommended. Any attempts at cleaning may irreversibly destroy the fragile mineral structure. If dust removal is necessary, a gentle stream of compressed air can be used from a safe distance. ## What to Avoid Contact with water, acids, bases, and other chemicals should be strictly avoided, as numanoite, being a carbonate, is susceptible to chemical reactions. It should be protected from ultrasound, high temperatures, and sudden temperature changes. Due to its microscopic nature, any vibrations and shocks should be avoided. ## Storage Specimens should be stored under stable conditions, in closed, padded "micromount" boxes that protect against dust, moisture, and mechanical damage. Store away from heat sources and direct sunlight.

External references

Sources

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