Macquartite

Chemical formula: Cu<sup>2+</sup><sub>2</sub>Pb<sup>2+</sup><sub>7</sub>(Cr<sup>6+</sup>O<sub>4</sub>)<sub>4</sub>(SiO<sub>4</sub>)<sub>2</sub>(OH)<sub>2</sub>

Macquartite is a very rare, orange-red lead, copper, and chromium mineral, occurring as microscopic crystals.

## Characteristics Macquartite is a complex lead and copper chromate and silicate. It forms prismatic, acicular, or bladed crystals, usually microscopic in size, rarely exceeding 1 mm in length. Most often, it occurs as radial aggregates or small clusters on the surface of the host rock. Its intense, orange-red color is its most characteristic visual feature. ## Physical Properties Macquartite crystals exhibit a luster described as adamantine to resinous. They are transparent to translucent. The Mohs hardness is approximately 3.5, and the density is high, approximately 6.95 g/cm³, which is typical for lead-rich minerals. ## Colors and Varieties This mineral is monochromatic and occurs exclusively in shades from orange to orange-red. No color or commercial varieties are distinguished. ## History and Name Macquartite was discovered in the Tiger mine in Pinal County, Arizona (USA). It was described in 1980 by Sidney A. Williams and Marjorie C. Duggan. The mineral is named in honor of Jean-Claude Macquart (1778–1855), a French chemist and writer, author of early works in mineralogical chemistry. ## Applications Due to its extreme rarity and microscopic crystal size, macquartite has no industrial applications. It is solely an object of interest for specialized mineral collectors (so-called micromounters) and scientists.

Properties

Mohs hardness
3.5
Luster
Adamantine to Resinous
Streak
Pale orange
Density
6.95
Cleavage
Perfect on {101}
Fracture
Uneven
Transparency
Transparent to Translucent
Crystal system
Monoclinic

Diagnostic features

## Identification Macquartite is primarily recognizable by its unique combination of features: intense orange-red color, occurrence as small, acicular crystals forming radial aggregates, and co-occurrence with other rare minerals from the Tiger mine. However, definitive identification requires advanced analytical methods such as X-ray diffraction (XRD) or chemical analysis (EDS). ## Distinguishing from Similar Minerals It can be confused with other orange or red secondary lead minerals, such as wulfenite, crocoite, or vanadinite. It differs from wulfenite by its crystal habit (acicular, not tabular). From crocoite, it differs by a harder, more adamantine luster and usually smaller crystal size. Vanadinite forms hexagonal crystals, while macquartite crystallizes in the monoclinic system. However, the locality and associated minerals are key. ## Crystal Forms Crystals are most often elongated, prismatic, acicular, or bladed. They usually form radial or stellate aggregates, as well as haphazard clusters on the rock surface.

Geological environment

## Genesis Macquartite is a secondary mineral, forming in the oxidation zones (gossans) of polymetallic deposits rich in lead and copper. Its formation requires specific geochemical conditions, including the presence of chromate ions (CrO₄)²⁻, which are very rare in the natural environment. The source of chromium at the type locality (Tiger mine) was likely oxidizing primary minerals, such as vanadinite containing chromium impurities. ## Mineral Associations This mineral co-occurs with a number of other rare secondary minerals, especially from the type locality. It is most often accompanied by: dioptase, wulfenite, cerussite, chrysocolla, hematite, quartz, as well as other rare lead chromates and silicates such as phoenicochroite, hemihedrite, or wickenburgite. ## Localities The only confirmed and well-documented locality for macquartite worldwide is its discovery site – the Tiger mine in the Mammoth-Saint Anthony Mine district, Pinal County, Arizona, USA. This is a classic locality for many rare secondary minerals.

Rarity

Very rare

For collectors

## Quality Criteria The most highly valued macquartite specimens are those with well-formed, sharply terminated crystals forming aesthetic, radial aggregates. The intensity and purity of the orange-red color are crucial. Contrast with the matrix – usually whitish cerussite or quartz – is also important. Due to the microscopic nature of the mineral, the size of aggregates and individual crystals is of great significance, and specimens with crystals visible without high magnification are exceptionally desirable. ## Popular Localities The only source of collector specimens is the historic Tiger mine in Arizona, which has been inactive and inaccessible for many years. All specimens available on the market come from old collections, which further increases their value and rarity.

Care and storage

## Cleaning Specimens should be cleaned only very carefully, using compressed air to remove dust. Any contact with water or chemicals is inadvisable. Due to the microscopic size of the crystals, mechanical cleaning (e.g., with a brush) is impossible and risks damaging the specimen. ## What to Avoid Avoid contact with all liquids, including water and cleaning agents. The mineral is sensitive to acids. Protect it from high temperatures, shocks, and ultrasound. As a mineral containing lead and chromium, it requires careful handling – avoid inhaling dust and wash hands after contact. ## Storage It is recommended to store specimens exclusively in specialized micromount boxes that protect them from dust, mechanical damage, and moisture. Exposure should be away from direct sunlight and heat sources.

Sources

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