Kupčíkite

Chemical formula: Cu<sub>3.4</sub>Fe<sub>0.6</sub>Bi<sub>5</sub>S<sub>10</sub>

Kupčíkite is a rare copper, iron, and bismuth sulfide, forming acicular crystals with a metallic luster.

## Characteristics Kupčíkite is a mineral from the sulfide class, belonging to the hodrushite group. It occurs as elongated, acicular (needle-like) or bladed crystals, which often form radial or tangled aggregates. Individual crystals rarely exceed a few millimeters in length. It is opaque and has a metallic luster. ## Physical Properties This mineral is characterized by a metallic luster and a black streak. It is relatively soft, with a Mohs hardness of approximately 3.5. It is a brittle mineral. ## Colors and Varieties Kupčíkite is steel-gray to black in color. Some specimens may exhibit a delicate brownish or iridescent surface tarnish, which is a result of oxidation. ## History and Name The mineral's name honors Professor Vladimír Kupčík (1934-2022), a crystallographer from the University of Göttingen (Germany), for his contributions to the crystal chemistry of bismuth sulfides and sulfosalts. The mineral was approved by the IMA in 2001, and its discovery was described in 2002 based on specimens from Slovakia and the Czech Republic. ## Uses Due to its rarity and small crystal size, kupčíkite has no industrial applications. It is solely an object of interest for collectors specializing in rare minerals and for scientists.

Properties

Mohs hardness
3.5
Luster
Metallic
Streak
Black
Density
6.45
Cleavage
Perfect on {010}
Fracture
Uneven
Transparency
Opaque
Crystal system
Monoclinic

Diagnostic features

## Identification Kupčíkite is identified by its characteristic form – thin, acicular or bladed crystals of a steel-gray color and metallic luster. It often forms tangled or radial aggregates. Its co-occurrence with other bismuth sulfides and sulfosalts is also key. ## Distinguishing from Similar Minerals It can be confused with other acicular bismuth sulfosalts, such as bismuthinite, aikinite, or emplectite. Final differentiation from these minerals often requires advanced analytical methods, such as chemical composition analysis (EDS) or X-ray diffraction (XRD), as they are visually very similar. ## Crystal Forms Crystals are strongly elongated, acicular, bladed, often with visible longitudinal striations. They usually occur as tangled aggregates, radial clusters, or chaotically arranged needles grown on other minerals, mainly quartz.

Geological environment

## Genesis It is a hydrothermal mineral, forming in ore veins. It crystallizes at medium to low temperatures in paragenesis with other bismuth, copper, and lead sulfides and sulfosalts. ## Mineral Associations It most commonly co-occurs with bismuthinite, emplectite, hodrushite, chalcopyrite, pyrite, quartz, and native bismuth. Depending on the locality, other rare sulfosalts may also accompany it. ## Localities The most important and classic localities for this mineral are: - **Slovakia**: Ľubietová (Libethen), particularly the Podlipa deposit, where it was discovered (type locality). - **Czech Republic**: Horní Slavkov (Schlaggenwald) in the Slavkov Forest. - **Japan**: Ikuno Mine in Hyōgo Prefecture on Honshu Island.

Rarity

Very rare

For collectors

## Quality Criteria Specimens with well-formed, sharp, and undamaged acicular crystals are most valued by collectors. Rich, radial aggregates or dense clusters of needles on a contrasting matrix, most often white quartz, are highly prized. The size of the crystals is also important – specimens with needles exceeding a few millimeters are rare. The purity of the specimen and the absence of mechanical damage are crucial. ## Popular Localities Specimens from the type locality, Ľubietová in Slovakia, have the greatest historical and scientific value. Specimens from Horní Slavkov in the Czech Republic and the Ikuno Mine in Japan also appear on the collector's market and are equally sought after by specialists.

Care and storage

## Cleaning Specimens should only be cleaned mechanically, using a soft brush to remove dust. The use of water or any chemical agents that could react with the sulfides and cause oxidation or damage is not recommended. ## What to Avoid Avoid contact with water, acids, detergents, and other chemicals. The mineral is sensitive to moisture, which can lead to its slow oxidation and the formation of tarnish. It should be protected from high temperatures and sudden temperature changes. ## Storage It is recommended to store specimens in a dry place, preferably in tightly sealed "membrane boxes" or in display cases away from moisture. Limiting air access will slow down oxidation processes and help preserve the mineral's natural luster.

Sources

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