Hydroxykenomicrolite

Chemical formula: (&#9744;,Na,Sb<sup>3+</sup>)<sub>2</sub>Ta<sup>5+</sup><sub>2</sub>O<sub>6</sub>(OH)

Hydroxykenomicrolite is an extremely rare mineral from the pyrochlore supergroup, forming small, octahedral crystals with a high tantalum content.

## Characteristics Hydroxykenomicrolite is a mineral belonging to the pyrochlore supergroup and the microlite group. It occurs as very small, but well-formed, sharp crystals, most often taking the form of an octahedron. Its surface is characterized by a strong, resinous or even adamantine luster. It is usually opaque, less often translucent at the edges. ## Physical Properties This mineral has a hardness of 5 on the Mohs scale and a significant density, reaching approximately 6.33 g/cm³, which is typical for tantalum-rich minerals. It is brittle, and its fracture is subconchoidal to uneven. It does not exhibit distinct cleavage. ## Colors and Varieties Hydroxykenomicrolite ranges in color from yellowish-brown, through reddish-brown, to dark brown. Its streak on a porcelain plate is light brown. No color or commercial varieties are distinguished. ## History and Name The mineral's name, approved by the International Mineralogical Association (IMA) in 2010, reflects its chemical composition. The prefix "hydroxy-" indicates the presence of a hydroxyl group (OH), "keno-" refers to a vacancy at the A-site in the crystal structure, and "microlite" refers to its belonging to the microlite group. The mineral is the result of a redefinition of previously described, but inaccurately studied, microlites. ## Applications Due to its extreme rarity and occurrence as very small crystals, hydroxykenomicrolite has no industrial applications. It is solely an object of scientific interest and a prized acquisition for specialized collectors of rare minerals.

Properties

Mohs hardness
5
Luster
Adamantine, Resinous
Streak
Light brown
Density
6.33
Cleavage
Indistinct on {111}
Fracture
Subconchoidal
Transparency
Translucent to opaque
Crystal system
Isometric

Diagnostic features

## Identification Features facilitating identification in a collection are: crystal habit (perfect octahedra), high density (the specimen is heavy for its size), resinous or adamantine luster, and occurrence environment (granitic pegmatites). However, final confirmation of identity requires advanced chemical analysis (e.g., EDS), as distinguishing it from other minerals in the microlite group is visually impossible. ## Distinguishing from Similar Minerals Hydroxykenomicrolite can be confused with other minerals from the pyrochlore supergroup (e.g., fluorocalciomicrolite, oxykenomicrolite), from which it differs in chemical composition. It can also be similar to small crystals of zircon, cassiterite, or sphalerite. Zircon is much harder (7.5), and cassiterite has a higher density and often a different crystal habit. ## Crystal Forms It most often forms single, euhedral (well-formed) crystals in the form of an octahedron {111}, less often a rhombic dodecahedron. Crystals are usually small, not exceeding a few millimeters in size.

Geological environment

## Genesis It is a secondary mineral, formed in the late stages of hydrothermal processes or as a result of metasomatism in zones of highly differentiated granitic pegmatites, especially of the LCT (lithium-cesium-tantalum) type. It forms as a result of alterations of primary tantalum minerals. ## Mineral Associations It most often co-occurs with other pegmatitic minerals, such as albite, lepidolite, elbaite, tantalite-(Mn), cassiterite, and other rare tantalum and niobium minerals. ## Localities The most important and type locality for hydroxykenomicrolite is the Muiâne pegmatite, in the Alto Ligonha district, Zambézia Province, Mozambique. It is also known from the Volta Grande pegmatite in Minas Gerais state, Brazil. Occurrences have also been reported in several other localities worldwide, but specimens from these are usually microscopic in size.

Rarity

Extremely rare

For collectors

## Quality Criteria The most highly prized specimens are those with sharp, fully formed, lustrous crystals of the largest possible size. Their placement on a contrasting matrix, such as white albite or purple lepidolite, is highly desirable, as it enhances the crystal's color and form. Purity and lack of damage are crucial. ## Popular Localities By far the most well-known and valued by collectors are specimens from the type locality in Muiâne, Mozambique. Most of the well-formed crystals available on the collector's market originate from there.

Care and storage

## Cleaning Hydroxykenomicrolite specimens should only be cleaned mechanically, using a soft brush to remove dust. If necessary, distilled water can be used. Ultrasonic cleaners should be avoided, as they can cause cracks in brittle crystals. ## What to Avoid The mineral is sensitive to strong acids and bases. Contact with household and laboratory chemicals should be avoided. It should not be subjected to sudden temperature changes. ## Storage It is recommended to store specimens in separate, sealed collector boxes to protect them from dust and mechanical damage. It is stable and does not require protection from light.

External references

Sources

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