Hodrušite

Chemical formula: Cu<sup>1+</sup><sub>4</sub>Bi<sup>3+</sup><sub>6</sub>S<sup>2-</sup><sub>11</sub>

Hodrushite is a rare copper-bismuth sulfide, forming acicular crystals with a metallic luster, found in hydrothermal veins.

## Characteristics Hodrushite is a mineral from the sulfide group, chemically classified as a copper-bismuth sulfide. It is rare, forming characteristic, elongated, acicular or bladed crystals, which often arrange themselves into radial or tangled aggregates. Individual crystals rarely exceed a few millimeters in length. The mineral is opaque and has a metallic luster, and its color on a fresh surface is tin-white to steel-gray, often with a brownish tint. ## Physical Properties The Mohs hardness of hodrushite is approximately 4, making it a relatively soft mineral. It is brittle, and its density is significant, around 6.45 g/cm³. The luster is distinctly metallic. This mineral exhibits perfect cleavage in one direction. ## Colors and Varieties This mineral is monocolored. Its color ranges from tin-white, through steel-gray, to grayish-white with a brownish tint. On surfaces exposed to air, it may tarnish or become covered with a patina of secondary copper minerals. ## History and Name Hodrushite was first described in 1970 by M. Koděra, V. Kupčík, and E. Makovický. Its name comes from the discovery locality – the Banská Hodruša deposit (now Hodruša-Hámre) in Slovakia, which is its type locality. This is an important mining center with a long history, known for the occurrence of many ore minerals. ## Uses Due to its rarity, hodrushite has no industrial application. It is solely an object of interest for collectors specializing in rare ore minerals and scientists studying sulfide parageneses.

Properties

Mohs hardness
4
Luster
Metallic
Streak
Black
Density
6.45
Cleavage
Perfect on {010}
Fracture
Uneven
Transparency
Opaque
Crystal system
Monoclinic

Diagnostic features

## Identification Hodrushite can be identified by its characteristic form – long, acicular or bladed crystals, often forming radial aggregates. Key features also include a metallic luster, tin-white or steel-gray color, and high density. It occurs in paragenesis with other sulfides and sulfosalts of bismuth and copper. ## Distinguishing from Similar Minerals Hodrushite can be confused with other acicular sulfosalts, such as bismuthinite (Bi₂S₃) or aikinite (PbCuBiS₃). Bismuthinite is usually more lead-gray and has a slightly lower hardness. Aikinite often forms thicker, prismatic crystals. Definitive distinction requires advanced analytical methods, such as chemical analysis (EDS) or X-ray diffraction (XRD). ## Crystal Forms Hodrushite crystals are elongated along one axis, forming acicular, bladed, or hair-like shapes. They usually occur as radial, stellate, or haphazardly tangled aggregates. Less commonly, they are found as single crystals embedded in quartz.

Geological environment

## Genesis Hodrushite is a mineral of hydrothermal origin. It forms in medium to high-temperature (meso- and hypothermal) ore veins that cut through volcanic rocks, such as andesites and dacites. It crystallizes from solutions rich in copper, bismuth, and sulfur. ## Mineral Associations This mineral often co-occurs with other sulfides and sulfosalts. Its most common associated minerals include chalcopyrite, bismuthinite, quartz, hematite, pyrite, as well as other rarer bismuth minerals, such as emplectite, wittichenite, or paderaita (of which hodrushite is a dimorph). ## Localities The most important and classic occurrence of hodrushite is its type locality – the Rozália deposit in Hodruša-Hámre, Slovakia. It is also known from several other locations worldwide, including the Botevo mine in Bulgaria, the Ulsan deposit in South Korea, the Salave mine in Spain, and several sites in Japan (Oya and Kushikino mines).

Rarity

Rare

For collectors

## Quality Criteria The most valued specimens by collectors are those with well-formed, sharp, and undamaged crystals, forming aesthetic, radial aggregates. The contrast with clear quartz, on which the crystals are embedded, significantly enhances visual appeal. The size of the aggregates and the luster of the crystals also have a significant impact on the specimen's value. Confirmed analysis, distinguishing it from similar sulfosalts, is also important. ## Popular Localities By far the most sought-after and classic specimens come from the type locality – the Rozália mine in Hodruša-Hámre, Slovakia. Specimens from this location are considered exemplary for the species and fetch the highest prices in the collector's market.

Care and storage

## Cleaning Hodrushite specimens are very delicate and brittle. Cleaning should be limited to an absolute minimum. If necessary, a soft brush can be used to remove dust. Water and any chemicals that could cause oxidation or damage to the delicate crystals should be avoided. ## What to Avoid Contact with water, acids, detergents, and other chemicals must be strictly avoided. The crystals are very brittle, so the specimen should be protected from impacts, vibrations, and abrasion. Prolonged exposure to humid air can lead to oxidation and surface tarnishing. ## Storage It is recommended to store hodrushite specimens in closed, dry containers (e.g., "micromount" boxes) away from dust and moisture. To prevent oxidation, desiccants can be used. Due to its brittleness, the specimen should not be placed in direct contact with other, harder minerals.

Sources

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