Guimarãesite

Chemical formula: Ca₂Zn²⁺₅Be₄(PO₄)₆(OH)₄·6H₂O

Guimarãesite is a very rare, hydrated beryllium, zinc, and calcium phosphate, forming spherical aggregates of tiny, platy crystals.

## Characteristics Guimarãesite is a very rare mineral from the phosphate group, chemically classified as a hydrated beryllium, zinc, and calcium phosphate. It occurs in the form of small, spherical or hemispherical aggregates, reaching up to 2 mm in diameter. These aggregates are composed of densely packed, elongated, platy crystals, only a few micrometers thick. ## Physical Properties Guimarãesite crystals exhibit a silky luster. Due to their small size and mode of occurrence, most physical properties, such as hardness, density, or transparency, have not been precisely determined. ## Colors and Varieties This mineral is colorless to white. No varieties have been distinguished. ## History and Name Guimarãesite was discovered in a granitic pegmatite in the Jocão mine, in the municipality of Conselheiro Pena (Minas Gerais, Brazil). It was approved as a new mineral species by the International Mineralogical Association (IMA) in 2004 (IMA2004-037). The name honors the Brazilian mining engineer, chemist, and geologist Djalma Guimarães (1894–1973), for his contributions to the study of Brazilian granitic pegmatites. ## Uses Guimarãesite has no industrial application. Its significance is purely scientific and collectible due to its extreme rarity.

Properties

Mohs hardness
4.5
Color
brown
Luster
Silky
Streak
White
Density
0
Cleavage
perfect cleavage on {100} and good cleavage on {010} (by analogy)
Fracture
Irregular/Uneven
Transparency
Transparent
Crystal system
Monoclinic

Diagnostic features

## Identification Identification of guimarãesite is primarily based on its unique morphology – white, spherical aggregates composed of tiny, platy crystals. Its occurrence environment in association with other rare phosphates in granitic pegmatites is also characteristic. Definitive identification requires advanced analytical methods, such as Raman spectroscopy or chemical analysis (EDS). ## Distinguishing from Similar Minerals It can be confused with other secondary, white minerals forming coatings or spherulitic aggregates, such as wardite or strengite. Visual differentiation is practically impossible without knowledge of the mineral association and location. Guimarãesite is distinguished by its unique chemical composition, containing calcium, zinc, and beryllium simultaneously. ## Crystal Forms It forms spherical or hemispherical radial-fibrous aggregates, composed of very fine, platy or acicular crystals, elongated along the [100] axis.

Geological environment

## Genesis Guimarãesite is a secondary mineral, formed in the late stages of hydrothermal processes in complex granitic pegmatites, rich in phosphorus and beryllium. It forms in rock cavities and fissures as a result of the alteration of earlier phosphate and beryllium minerals. ## Mineral Associations This mineral co-occurs with other rare phosphates. In its type locality (Jocão mine), it was found in association with eosphorite, zanazziite, wardite, strengite, cyrilovite, frondelite, rockbridgeite, quartz, albite, and muscovite. ## Localities The only confirmed occurrence of guimarãesite in the world is its type locality: Jocão mine, Conselheiro Pena municipality, Doce River valley, Minas Gerais state, Brazil.

Rarity

Extremely rare

For collectors

## Quality Criteria The quality of a guimarãesite specimen primarily depends on the richness and definition of the spherical aggregates on the rock matrix. Specimens with numerous, well-formed, white spheres contrasting with the substrate are most valued. The absence of damage to these delicate structures is also important. Due to the microscopic nature of the mineral, the size of individual aggregates rarely exceeds 1-2 mm. ## Popular Localities The only source of specimens is the Jocão mine in Brazil, which makes every specimen from this locality extremely valuable for specialized collectors of rare and "micromount" type minerals.

Care and storage

## Cleaning Due to the delicate and fragile nature of the aggregates, mechanical or chemical cleaning is not recommended. Any attempts may lead to irreversible damage to the specimen. It is safest to leave it in its original state. ## What to Avoid Avoid contact with water, chemicals, ultrasound, and sudden temperature changes. Fragile aggregates are very susceptible to mechanical damage, so they should be handled with extreme caution. ## Storage Guimarãesite specimens should be stored in stable conditions, in a sealed "micromount" box, to protect them from dust, moisture, and physical damage. They should not be exposed to direct sunlight.

External references

Sources

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