Ferrivauxite

Chemical formula: Fe<sup>3+</sup>Al<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub>(OH)<sub>3</sub>·5H<sub>2</sub>O

Ferrivauxite is a rare iron and aluminum phosphate, forming aggregates of small, blue-green crystals, prized by systematic mineral collectors.

## Characteristics Ferrivauxite is a hydrated iron and aluminum phosphate, belonging to the vauxite group. It occurs as small, tabular or prismatic crystals, rarely exceeding a few millimeters in length. These crystals often form radial aggregates, rosettes, or dense, felted masses in rock fissures. Its most characteristic feature is its intense, blue-green color. ## Physical Properties This mineral is characterized by relatively low hardness, approximately 3 on the Mohs scale. It has a vitreous luster and is transparent to translucent. Its density is low, which is typical for hydrated minerals. ## Colors and Varieties Ferrivauxite occurs in shades from blue-green to greenish-blue. Its color is very characteristic and constitutes a key visual feature. No color or commercial varieties are distinguished. ## History and Name The mineral's name refers to its chemical composition – the dominance of iron (Latin: *ferrum*) – and its relation to the structurally similar vauxite. It was described as a new mineral in 1948 based on material from the Siglo XX mine in Bolivia. ## Applications Ferrivauxite has no industrial applications. It is solely a mineral of scientific and collecting interest, sought after for its rarity, attractive color, and crystal habit.

Properties

Mohs hardness
3
Luster
Vitreous
Streak
Light green
Density
2.43
Cleavage
Good on {010}
Fracture
Uneven
Transparency
Transparent to translucent
Crystal system
Triclinic

Diagnostic features

## Identification Ferrivauxite is primarily identified by its characteristic blue-green color, crystal habit (small, tabular or prismatic), and typical radial aggregates. Its occurrence in association with other rare phosphates in hydrothermal veins is also an important indicator. ## Distinguishing from similar minerals It can be confused with other minerals from the vauxite group, such as vauxite or metavauxite. Differentiation often requires advanced chemical (EDS) or crystallographic (XRD) analyses. It differs from vauxite by the dominance of ferric iron over ferrous iron. It can also be confused with turquoise, from which it is much softer and forms differently developed crystals. ## Crystal forms It forms small, tabular crystals with a prismatic habit, often elongated. It is most commonly found in the form of radial or spherulitic aggregates, as well as dense, felted masses covering the surfaces of rock fissures.

Geological environment

## Genesis Ferrivauxite is a secondary mineral, formed in the oxidation zones of ore deposits rich in phosphorus. It forms under low-temperature hydrothermal conditions, crystallizing in fissures and rock cavities. Its formation is associated with the weathering processes of primary phosphate and ore minerals. ## Mineral associations It most commonly co-occurs with other rare phosphates, such as vauxite, metavauxite, wavellite, quartz, cassiterite, and marcasite. The classic association comes from the type locality in Bolivia. ## Localities The most important and historically first occurrence of ferrivauxite is the Siglo XX tin mine in Llallagua, Potosí Department, Bolivia. This is the type locality, from which the world's best specimens of this mineral originate. Other confirmed occurrences are few and do not provide material of collecting significance.

Rarity

Very rare

For collectors

## Quality criteria The most highly prized ferrivauxite specimens are characterized by an intense, saturated blue-green color. The form of crystal development is also important – well-defined, radial aggregates and rosettes are sought after. Crystal size, though usually small, also affects value. Specimens on a light quartz matrix, contrasting with the mineral's color, are particularly attractive. ## Popular localities The only source of valuable collector specimens is the historic locality – the Siglo XX mine in Llallagua, Bolivia. Specimens from this location are considered mineralogical classics and the standard for this species.

Care and storage

## Cleaning Ferrivauxite specimens should be cleaned very carefully, using only distilled water and a soft brush to remove dust. Ultrasonic cleaners should be avoided, as they can damage delicate crystals. ## What to avoid The mineral is sensitive to chemicals, especially acids, which can damage it. Prolonged exposure to strong sunlight, which can cause fading, should be avoided. It is also sensitive to high temperatures, which can lead to dehydration and structural damage. ## Storage Collectible ferrivauxite specimens are best stored in closed boxes or display cases to protect them from dust and mechanical damage. Due to its low hardness, it should not be stored in contact with harder minerals.

Sources

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