Cupromakovickyite

Chemical formula: Cu¹⁺₄Ag¹⁺Pb²⁺₂Bi³⁺₉S²⁻₁₈

A rare sulfide of copper, silver, lead, and bismuth, forming microscopic, metallic inclusions in other minerals.

## Characteristics Cupropavonite is a complex sulfosalt from the pavonite group, occurring as very fine, anhedral (irregularly shaped) grains or lamellar inclusions in other minerals, mainly in hodrushite and kupcikite. Its maximum observed size is approximately 0.2 x 0.5 mm. It is opaque and has a metallic luster. In reflected light, its color is creamy white, often with a slight pinkish tint compared to the surrounding hodrushite. ## Physical Properties Due to the microscopic size of the grains, most physical properties, such as hardness, density, cleavage, or fracture, have not been precisely determined. The mineral is too small for standard tests. The density calculated based on the chemical formula and unit cell parameters is 7.01 g/cm³. ## History and Name The mineral was first described in 2008 by a team of mineralogists (Topa, Makovicky, Balic-Zunic, Paar). The name "cupropavonite" refers to its chemical composition – the dominance of copper (Latin: *cuprum*) – and honors Professor Emil Makovicky (born 1940), a mineralogist from the University of Copenhagen, for his contributions to the study of sulfosalts, including the lillianite and pavonite groups. It was approved by the International Mineralogical Association (IMA) under number 2007-048.

Properties

Mohs hardness
4-4.5
Color
Gray
Luster
Metallic
Streak
Gray
Density
6.78
Cleavage
None
Fracture
Irregular/Uneven
Transparency
Opaque
Crystal system
Monoclinic

Diagnostic features

## Identification Identification of cupropavonite is possible only through advanced laboratory methods, such as electron microprobe analysis (EDS/WDS) to determine chemical composition and X-ray diffraction (XRD) to confirm crystal structure. Visually, in a polished section under a microscope, it can be recognized as creamy white, slightly anisotropic inclusions in other sulfides. ## Distinguishing from similar minerals Under the microscope, it can be confused with other bismuth sulfosalts, such as pavonite, makovickyite, hodrushite, or kupcikite. Definitive differentiation requires quantitative chemical analysis, especially of the copper, silver, lead, and bismuth ratios. ## Crystal forms Cupropavonite occurs as anhedral (irregularly shaped) grains and lamellae not exceeding several hundred micrometers, most often as inclusions in hodrushite.

Geological environment

## Genesis Cupropavonite forms as a result of hydrothermal processes in ore veins. In the type locality (Banská Hodruša), it is a product of the alteration (solid-state decomposition) of a pre-existing mineral, kupcikite, at temperatures below 312 °C. This process leads to the formation of intergrowths of cupropavonite and hodrushite. ## Mineral associations This mineral coexists with hodrushite, kupcikite, pavonite, makovickyite, quartz, hematite, and chalcopyrite. ## Localities The only confirmed and detailed described locality of cupropavonite in the world is the Rozália vein in Banská Hodruša (Hodruša-Hámre) in the Štiavnica Mountains, Slovakia. This is its type locality.

Rarity

Extremely rare

For collectors

## Quality criteria Cupropavonite does not form macroscopic specimens, therefore it is not an object of collector's trade in the traditional sense. Its value is purely scientific. For research institutions and specialized systematic collections, the only criterion is to possess a sample from the type locality where the presence of the mineral has been confirmed by analysis. The visual attractiveness of the specimen depends solely on the host mineral in which cupropavonite occurs as a microscopic inclusion.

Care and storage

## Cleaning Specimens containing cupropavonite, being microscopic inclusions, practically do not require cleaning. If it is necessary to remove dust from the matrix mineral, only compressed air or a very soft brush should be used. ## What to avoid Avoid all wet cleaning methods and the use of ultrasonics, which could damage the delicate surface of the host mineral. As a sulfide, it is potentially sensitive to chemicals and oxidation in a humid environment, which can lead to its degradation. ## Storage Specimens should be stored under stable conditions, in a dry environment, away from direct sunlight and chemical contaminants. The best solution is a sealed collector's box or display case.

External references

Sources

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