Amphibole

Chemical formula: (Ca,Na)₂(Mg,Fe,Al)₅(Al,Si)₈O₂₂(OH)₂

Amphiboles are an important and diverse group of common, dark rock-forming minerals with complex chemical compositions and characteristic elongated crystals.

## Characteristics Amphiboles are a large and complex group of inosilicate minerals, comprising several dozen distinct minerals. It is not a single mineral, but a supergroup whose individual members share a common crystal structure based on double chains of silicon-oxygen tetrahedra. Typical specimens are elongated, prismatic, or acicular crystals, often forming radial or fibrous aggregates. The most well-known representatives are hornblende, actinolite, and tremolite. Due to their prevalence, amphiboles are key rock-forming minerals in many igneous and metamorphic rocks, such as granites, diorites, amphibolites, and schists. ## Physical Properties Minerals of the amphibole group exhibit a hardness ranging from 5 to 6 on the Mohs scale. Their luster is typically vitreous, and in the case of fibrous varieties, it can be silky. Density varies depending on chemical composition (mainly iron content) and ranges from approximately 2.9 to 3.6 g/cm³. A characteristic feature is perfect cleavage in two directions, intersecting at angles of approximately 56° and 124°, which is a key feature distinguishing them from similar pyroxenes. ## Colors and Varieties The color of amphiboles is highly varied and depends on their chemical composition. Tremolite, rich in magnesium, is usually white, gray, or light green. Actinolite, containing iron, ranges in color from green to dark green. Hornblende, with the most complex composition, is most often black or dark greenish-brown. Other amphiboles, such as glaucophane, impart a bluish hue to rocks (blueschists), and riebeckite can be dark blue. Fibrous varieties, such as nephrite (a variety of actinolite) or crocidolite (asbestiform riebeckite), have gemmological or industrial significance. ## History and Name The name "amphibole" comes from the Greek word *amphíbolos* (ἀμφίβολος), meaning "ambiguous" or "doubtful". It was introduced by the French mineralogist René Just Haüy in 1797. This name accurately reflects the enormous variability in appearance and chemical composition encountered by early mineralogists attempting to classify these minerals. ## Uses Some amphiboles have specific uses. Nephrite, a compact, fibrous variety of actinolite, is a valuable ornamental and gem material, known as one form of jade. Fibrous varieties, known collectively as amphibole asbestos (e.g., crocidolite, amosite), were widely used in the past as insulating and fire-resistant materials. Currently, their use is drastically restricted or prohibited due to proven health hazards (carcinogenic effects). Additionally, amphiboles are important indicators of pressure and temperature conditions for geologists studying rock history.

Properties

Mohs hardness
5-6
Luster
Vitreous, silky
Streak
White to grayish-green
Density
2.9-3.6
Cleavage
Perfect in two directions, angles ~56° and 124°
Fracture
Uneven, splintery
Transparency
Translucent to opaque
Crystal system
Monoclinic

Diagnostic features

## Identification The key diagnostic feature of amphiboles is the angle between the two cleavage planes, which is approximately 124° and 56°. In practice, on fractured crystal surfaces, two sets of shiny "steps" intersecting at these angles are visible. The elongated, prismatic, or acicular crystal habit and a hardness range of 5-6 on the Mohs scale are also helpful. ## Distinguishing from Similar Minerals Amphiboles are most often confused with pyroxenes, which have a very similar appearance, hardness, and often occur in the same rocks. The primary difference is the cleavage angle: in pyroxenes, cleavage planes intersect at an angle close to 90° (approx. 87° and 93°). As a result, the cross-section of an amphibole crystal is rhombic, while that of a pyroxene is square or rectangular. Tourmaline, although also sometimes prismatic and black, is much harder (7-7.5) and has a different, more complex cross-section (often a rounded triangle). ## Crystal Forms Amphiboles form crystals with prismatic, columnar, acicular, or fibrous habits. They often occur as granular, radial (as in variolite), fibrous (nephrite, asbestos), or tangled aggregates. Well-formed, freestanding crystals are rarer and found mainly in metamorphic rocks and pegmatites.

Geological environment

## Genesis Amphiboles are minerals with a wide range of formation conditions. They crystallize as primary components from intermediate, water-rich magmas, forming rocks such as diorites, andesites, and syenites. They are also secondary products, formed by the hydration of pyroxenes (a process called uralitization). However, they are most significant in metamorphic rocks, where their presence defines the entire amphibolite facies – conditions of medium to high pressures and temperatures. They then form through the alteration of basalts, gabbros, or marls, creating rocks known as amphibolites. ## Mineral Associations As rock-forming minerals, amphiboles coexist with many other common minerals. In igneous rocks, these are most often plagioclase, potassium feldspar, quartz, and biotite. In metamorphic rocks, their typical associates are plagioclase, epidote, garnets (especially almandine), staurolite, kyanite, and sillimanite. In contact metamorphic rocks (hornfels), they occur with cordierite and andalusite. ## Localities Amphiboles are widespread globally. Classic localities for well-formed hornblende crystals include the Bancroft area in Ontario (Canada), Arendal (Norway), and Franklin, New Jersey (USA). Beautiful, green actinolite crystals come from the Zillertal Valley in Austria. Tremolite is common in metamorphic dolomites in the Campolungo region in Switzerland and in New York State (USA). Blue riebeckite in the form of crocidolite is known from South Africa, and glaucophane from the island of Syros in Greece and California (USA).

Rarity

Common

For collectors

## Quality Criteria For collectors, the most desirable specimens are those with well-formed, sharp, and lustrous crystals that are clearly distinct from the surrounding rock (matrix). Large, single crystals or aesthetic crystal groups are highly valued. In the case of hornblende and actinolite, the depth and saturation of color and the absence of damage are important. Rare varieties, such as blue riebeckite or purple richterite, are particularly sought after. For fibrous varieties, such as nephrite, color uniformity, translucency, and absence of cracks are assessed. ## Popular Localities The most prized hornblende crystals by collectors come from the Canadian province of Ontario (Bancroft and Wilberforce areas). Classic, large tremolite and actinolite crystals were found in the Alps (Switzerland, Austria). Gem-quality pargasite specimens come from Pakistan (Hunza Valley), and purple richterite from Wind Mountain in New Mexico (USA).

Care and storage

## Cleaning Amphibole specimens are relatively hard and can be cleaned with a soft brush under running water. For specimens with delicate, acicular crystals, special care should be taken, limiting cleaning to gentle rinsing or using compressed air to remove dust. Fibrous (asbestiform) varieties should not be mechanically cleaned to avoid releasing fibers into the air. ## What to Avoid Avoid contact with strong acids, which can etch the mineral surface. Despite relatively good resistance, specimens should not be exposed to sudden temperature changes. The greatest caution should be exercised with asbestiform varieties (crocidolite, amosite) – absolutely avoid inhaling dust and fibers that may be released from them. ## Storage Amphibole specimens can be safely stored in collections. Due to their excellent cleavage, they should be protected from impacts and falls, which can cause breakage along cleavage planes. Specimens of asbestiform varieties should be stored in sealed, closed containers to prevent the spread of fibers.

External references

Sources

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